By El Sayed H. El Ashry and Ahmed A. Kassem
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Extra info for Account of microwave irradiation for accelerating organic reactions
High yield, highly selective, and catalytic. , a series of ruthenium-catalyzed reactions for carbon–carbon bond formation at unactivated 48 F. Kakiuchi · N. Chatani C–H bonds. In this section, among the transition-metal-catalyzed C–H/olefin coupling, ruthenium-catalyzed reactions will mainly be discussed. (5) The pioneering study of ruthenium-catalyzed regioselective alkylation using olefins as an alkylating reagent was reported by Lewis and Smith . The ortho-selective ethylation of phenols with ethylene can be attained with the aid of a ruthenium(II) phosphite complex as a catalyst.
4 Reaction of Aromatic Compounds Addition to Olefins . . . . . Addition to Acetylenes . . . . Arylation . . . . . . . Silylation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 . . . 47 47 60 61 62 3 Addition of Olefinic and Aliphatic C–H Bonds to C–C Multiple Bonds . . 1 Addition to Olefins . . . . . . . . . . .
Renaud JL, Bruneau C, Demerseman B (2003) Synlett 408 115. Mbaye MD, Demerseman B, Renaud JL, Toupet L, Bruneau C (2003) Angew Chem Int Ed Engl 42:5066 116. (a) Tsuji Y, Mukai T, Kondo T, Watanabe Y (1989) J Organomet Chem 369:C51; (b) Kondo T, Ono H, Satake N, Mitsudo T-a, Watanabe Y (1995) Organometallics 14: 1945 44 Ruthenium-Catalyzed C–C Bond Formation 117. Kondo T, Hiraishi N, Morisaki Y, Wada K, Watanabe Y, Mitsudo T-A (1998) Organometallics 17:2131 118. (a) Nishibayashi Y, Inada Y, Hidai M, Uemura S (2003) J Am Chem Soc 125:6060; (b) Nishibayashi Y, Onodera G, Inada Y, Hidai M, Uemura S (2003) Organometallics 22:873; (c) Nishibayashi Y, Inada Y, Hidai M, Uemura S (2002) J Am Chem Soc 124: 7900 119.
Account of microwave irradiation for accelerating organic reactions by El Sayed H. El Ashry and Ahmed A. Kassem